PALAIOS
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PALAIOS; January 2007; v. 22; no. 1; p. 98-103; DOI: 10.2110/palo.2005.p05-089r
© 2007 SEPM Society for Sedimentary Geology
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OXYGEN ISOTOPIC COMPOSITION OF BIOGENIC PHOSPHATE AND THE TEMPERATURE OF EARLY ORDOVICIAN SEAWATER

DAMON BASSETT*,1, KENNETH G. MACLEOD1, JAMES F. MILLER2 and RAYMOND L. ETHINGTON1

1 Department of Geological Sciences, University of Missouri, Columbia, Missouri 65211, USA;
2 Department of Geography, Geology, and Planning, Missouri State University, Springfield, Missouri 65897, USAbassettd{at}missouri.edu

Stable isotopic values were measured on micrite, sparry calcite, dolomite, inarticulated brachiopods, and conodonts from the Lange Ranch section (central Texas) of the Lower Ordovician Tanyard Formation. The section spans the upper Cordylodus angulatus Zone through the lower Rossodus manitouensis Zone. An ~2{per thousand} negative {delta}13C shift from >0{per thousand} to <–1.5{per thousand}VPDB through the section suggests the lower third of the Rossodus manitouensis Zone was sampled. Consistent with previous studies, the {delta}18O values of carbonates are low, ranging from –3.3{per thousand} to –8.1{per thousand}VPDB. Phosphate {delta}18O values range from 15.4{per thousand} to 17.1{per thousand}VSMOW. Paleotemperature estimates calculated from micrite {delta}18O values assuming an ice-free seawater {delta}18O value of –1{per thousand}VSMOW indicate Early Ordovician tropical seawater temperatures averaged 42°C, whereas {delta}18O values of co-occurring biogenic phosphate assuming the same seawater value yield paleotemperature estimates averaging 37°C. The phosphate values are interpreted as less affected by diagenesis than carbonate values and suggest Early Ordovician tropical paleotemperatures were not more than 10°C warmer or the oxygen isotopic composition of Early Ordovician hydrosphere was not more than 2{per thousand} lower than present.




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J. A. Trotter, I. S. Williams, C. R. Barnes, C. Lecuyer, and R. S. Nicoll
Did Cooling Oceans Trigger Ordovician Biodiversification? Evidence from Conodont Thermometry
Science, July 25, 2008; 321(5888): 550 - 554.
[Abstract] [Full Text] [PDF]




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